Ans: a) CH4 + 2O2 -->CO2 + 2H2O + 891 kJ
Chemical reactions can be broadly classified as: Exothermic and endothermic reactions.
Exothermic reactions proceed with the release of heat. Here the potential energy of the reactants is greater than that of the products and the reaction enthalpy is negative.
In contrast, Endothermic reactions proceed with the absorption of heat. Here the potential energy of the reactants is lower than that of the products and the reaction enthalpy is positive.
In the given examples only
CH4 + 2O2 -->CO2 + 2H2O + 891 kJ
is an exothermic reaction as it involves production or release of 891 kJ of heat.
The other reactions are endothermic since they involve absorption of heat.