Media 1 and 2 are air and liquid. By Snell's law;
n1/n2 = Sin ∅2/Sin ∅1
Then,
n2 = (n1* Sin Ф1)/Sin ∅2 = (1*Sin 31.7)/Sin 21.3 = 1.4466.
When the light travels in the opposite direction and at critical angle, media 1 and 2 are liquid and air respectively while ∅2 = 90°
Therefore,
n1/n2 = Sin 90 / Sin ∅c => ∅c = Sin ^-1[n2*Sin 90]/n1 = Sin ^-1[1*Sin 90]/1.4466 = 43.73°
The critical angle (∅c) is 43.73°.