If Tim has blue eyes, then both of his parents are heterozygous for the brown eye trait.
Here would be the alleles:
BB-Homozygous Dominant for brown eyes
Bb-Heterozygous for brown eyes
bb-Homozygous Recessive for blue eyes
If you input the heterozygous allele for brown eyes into a punnet square, you would get a 25% chance of homozygous brown eyes, 50% chance of heterozygous brown eyes and a 25% chance of homozygous recessive blue eyes. Tim is that 25% that received a trait for blue eyes.