Final answer:
The molar solubility of BaSO4 in water, with a Ksp of 1.0 x 10^-10, is calculated by setting up the equilibrium expression Ksp = x^2 and solving for x, obtaining a molar solubility of 1.0 x 10^-5 M.
Step-by-step explanation:
To calculate the molar solubility of BaSO4 in water with a given Ksp of 1.0 x 10-10, we'll write the equilibrium expression for its dissolution:
Ksp = [Ba2+][SO42-]
Since the stoichiometric coefficients of BaSO4 dissolution into Ba2+ and SO42- are a 1:1 ratio, we can express the concentrations of the ions in terms of a single variable, x, where x represents the molarity of Ba2+ and SO42-. Therefore, the Ksp expression becomes:
Ksp = x2
Solving for x:
x2 = 1.0 x 10-10
x = \(\sqrt{1.0 x 10-10}\)
x = 1.0 x 10-5 M
Hence, the molar solubility of BaSO4 in water at 25°C is 1.0 x 10-5 M.