According to
Graham's Law of Diffusion," Diffusion of Gas is inversely proportional to square root of its Molecular Mass or Density".
rᵇ/rᵃ =

Or,
rᵇ/rᵃ =

----- (1)
As,
Ma = 275 g/mol
Mb = 205 g/mol
Putting Values in eq.1,
rᵇ/rᵃ =

rᵇ/rᵃ = 1.15
Result: Perfume B will diffuse 1.15 times faster than
Perfume A. Hence, Perfume B will be first smelled by the person.