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Based on your knowledge of intermolecular forces, which of the following would you expect to have the highest boiling point? hexanal hexane hexanone hexanol

2 Answers

7 votes

Answer:

hexanol has the highest

Step-by-step explanation:

User Jeiea
by
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6 votes
Answer:
Hexanol has the highest boiling point.

Step-by-step explanation:
Boiling points of all give compounds are as follow,

Hexanol = 157 °C

Hexanal = 129 °C

Hexanone = 128 °C

Hexane = 68 °C

Types of Interactions found in these compounds are,

Hexanol = Hydrogen Bonding & London Dispersion Forces

Hexanal = Dipole-Dipole Interactions & London Dispersion Forces

Hexanone = Dipole-Dipole Interactions & London Dispersion Forces

Hexane = Only London Dispersion Forces

Strength of Intermolecular Forces:
Hydrogen forces are stronger than Dipole-Dipole Interactions, and Dipole-Dipole Interactions are stronger than London Dispersion Forces.

Result:
Hence, due to presence of strong Hydrogen Bond Interactions Hexanol has the highest Boiling Point.
User Brad Payne
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