Answer:
t = 21.5 min.
Step-by-step explanation:
Hello!
In this case, since the kinetics of a first-order reaction is:
![([A])/([A]_0)=exp(-kt)](https://img.qammunity.org/2022/formulas/chemistry/college/u2ixctzq6z8cx5qq1ochdnsxpzxwxa40an.png)
Thus, since we are given the 11.7 min for a 58.6-% consumption, we can compute the rate constant, k:
![ln(1-0.586)=-kt\\\\k=(ln(0.414))/(-t)=(-0.882)/(11.7min)=0.0754min^(-1)](https://img.qammunity.org/2022/formulas/chemistry/college/98b4ljp90stdi8ard1vqucuc1p7jp2ejgr.png)
Now, for the second problem, as the new consumption is 80.2%, we can compute the required time as shown below:
![ln(1-0.802)=-kt\\\\t=(ln(198))/(k) \\\\t=(-1.62)/(0.0754min^(-1))\\\\t=21.5min](https://img.qammunity.org/2022/formulas/chemistry/college/bmyybcj99grc8epssd0a7npaef7bvxsssb.png)
Best regards!