If we see the forces on the astronauts then there is only one force on each astronaut while they are in air.
This force is due to gravity of earth.
Now while the astronauts are in air and doing some activities then the net force on them is counterbalanced on them by centrifugal force.
so we can say the rate of fall of astronauts due to gravity is at same rate as the orbiting rate of the space shuttle.
this is given by

so all astronauts will experience the situation of free fall.