She has a higher probability if she replaces the card before drawing the second one.
The probability of drawing a heart the first time is 13/52. If she replaces the card, the probability of drawing a second heart would again be 13/52;
13/52(13/52) = 169/2704 = 0.0625.
However, if she does not replace it, the probability of drawing a second heart would be 12/52;
13/52(12/51) = 156/2652 = 0.0588.
The probability is higher with replacement.