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How does the rate of effusion of sulfur dioxide, so2, compare to that of helium (he)? (note: the molar masses are so2 = 64 g/mol; he = 4.0 g/mol.)?

User Wonton
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sulfur dioxide diffuses at one quarter the rate of helium :)
User Davut Engin
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Answer : The rate of effusion of helium gas is four times of the rate of effusion of sulfur dioxide gas.

Solution : Given,

Molar mass of sulfur dioxide gas = 64 g/mole

Molar mass of helium gas = 4.0 g/mole

According to the Graham's law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of gas.


R\propto \sqrt{(1)/(M)}

or,


(R_1)/(R_2)=\sqrt{(M_2)/(M_1)}

where,


R_1 = rate of effusion of sulfur dioxide gas


R_2 = rate of effusion of helium gas


M_1 = molar mass of sulfur dioxide gas


M_2 = molar mass of helium gas

Now put all the given values in the above formula, we get


(R_1)/(R_2)=\sqrt{(4.0g/mole)/(64g/mole)}


(R_1)/(R_2)=(1)/(4)

Therefore, from this we conclude that, the rate of effusion of helium gas is four times of the rate of effusion of sulfur dioxide gas.

User Gustavo Cardoso
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