3/5 and 5
In the first pair, the only numbers are 9 and 6. Converting 4 into a fraction leaves us with 4/1 - the only numbers in that pair are 1 and 4. In the final one, the only numbers are 2 and 7.
However, converting 5 gives 5/1. What this means is that the top and bottom numbers are not flipped in this pair, making it the odd one out.
Hope I helped!