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How does the structure of amino acids allow them to form a polypeptide

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Amino acids which are known to be linked by peptide bonds they form polypeptide chains.

Proteins are linear polymers are formed by way of linking an a-carboxy group of one amino acid to a-amino of different amino acids which have peptide bond. The formation which results from two amino acids which result in a loss of a water molecule. The best process of the reaction is hydrolysis.
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