Answer is: fluorine has the largest first ionization energy.
The ionization energy (Ei) is the minimum amount of energy required to remove the valence electron, when element lose electrons, oxidation number of element grows (oxidation process).
Nonmetals are far right in the main group and they have highest ionization energy, because they have many valence electrons.
First ionization energy means that element lost one valence electron, because in fluorine (smallest atomic number) that electron is closest to nucleus, it requires most energy.