Final answer:
Ice samples have a larger volume than water samples because ice's crystalline structure, formed by hydrogen bonds, creates empty spaces between molecules, making ice less dense. This unique structure arises as molecular motion decreases and temperature drops, leading to ice floating on water.
Step-by-step explanation:
The volume of the ice samples is larger than that of the ice water samples because ice has a unique crystalline structure due to hydrogen bonding. When water freezes and becomes ice, its molecules arrange in a rigid, lattice-like structure that maximizes hydrogen bonding but creates open spaces between the molecules. This structure leads to ice being less dense than liquid water, which in turn means that a given number of water molecules will occupy a larger volume as ice than as liquid water.
As temperature decreases and molecular motion reduces, less energy is present to break these hydrogen bonds, resulting in the intact and well-defined lattice structure of ice. Conversely, when ice melts, thermal motion disrupts the hydrogen-bonded structure, allowing the water molecules to pack more closely together and thereby increase the density. Therefore, ice is one of the very few substances whose solid form has a lower density than its liquid form at the freezing point, causing the solid form (ice) to float on the liquid (water).