To estimate in the proccess of adding decimals, round the decimal to the nearest whole number. Then, add those two whole numbers, which should be close to your exact answer.
Example:
5.42+7.92
5.42-->5
7.92-->8
5+8=13
Exact Answer:
1
7.92
5.42
+_________
13.34
The answer 13.34 is close to the estimate of 13 so the answer is reasonable.