Thus, the question would probably ask if the ring of gold is actually pure gold. For this, first there is a need to calculate the specific heat capacity of the calorimeter. If this equivalent to the specific heat for pure gold, then the gold ring is pure fold.
Qwater = mCdt = (50 g) × (4.18 J/gC) (31 - 23.7) = 1525.7 J
On the basis of conservation of energy,
Qwater = Qcalorimeter = mCdT = 1525.7
1525.7 = (10.5) (C) (78.3 - 31)
C = 3.072 J/gC
As the specific heat of the calorimeter is not equivalent to that of the pure gold (0.1291 J/gC), then the gold ring is not pure.