The total no. of possible outcomes of rolling a fair die = 6
The possible outcomes are 1, 2, 3, 4, 5 and 6
The event to occur is getting a no. greater than 4.
The no. of possible outcomes to get a no. greater than 4 = 2
So, probability of getting a no. greater than 4 = 2/6 = 1/3
If you get a no. greater than 4 for the first time, you win $80.
So, the probability to win $80 is 1/3.
The probability to roll the die again = 1 - (1/3) = 2/3
In the second chance, if you get a no. greater than 4 you win $20, else nothing.
Since the two events are dependent, P(X and Y) = P(X) * P(Y)
Probability of getting a no. greater than 4 in the second chance = (2/3) * (1/3) =2/9
Probability of win (either in 1st or 2nd chance) = 1/3 + 2/9 =5/9
Please check attachment for probability model.