1. ∠C = 90° (given)
2. ∠A + ∠B + ∠C = 180° (Sum of ∠s in triangle)
3. ∠A + ∠B +90° = 180° (Substitution)
4. ∠A + ∠B = 90° (Algebra)
5. ∠A and ∠B are complementary (Def of complementary angles)
You could also construct an exterior angle from ∠C and prove it that way but that might be longer and more complicated.