Answer:
The Rock does not contain carbonate in it.
Step-by-step explanation:
Limestone(CaCO_3) when reacts with a acid produces carbon dioxide, which comes out as bubbles in the solution. It means the 4th rock does not have carbonate in it. Carbonate minerals are unstable in contact with hydrochloric acid. When acid begins to effervesce (fizz) on a specimen. These bubbles confirms the presence of carbonate in mineral.