K₃PO₄ → 3K⁺ (aq) + PO₄³⁻(aq)
One mole of PO₄³⁻ ion gets dissociated from one mole of K₃PO₄
As per the definition of Avogadro's number, 1 mole = 6.022 x 10²³ ions
One mole of PO₄³⁻ ions x (6.022 x 10²³ ions/ 1 mole of PO₄³⁻ ions )
= 6.022 x 10²³ ions
Therefore , there are 6.022 x 10²³ PO₄³⁻ ions in a mole of K₃PO₄.