Answer :
(D)
(C)
(B)
(A)
_
_
(B)
_
(C)
BaS
Explanation :
(1) Reaction for A + B
+
2KCl +

In this reaction, there is no precipitate formed as the products are souble.
(2) Reaction for A + C
+
+

In this reaction,
is formed as precipitate as it do not dissolve.
(3) Reaction for A + D
+
+

In this reaction, there is no precipitate formed as the products are souble.
(4) Reaction for B + D
+

In this reaction,
is formed as precipitate as it do not dissolve.
(5) Reaction for B + C
+
+

In this reaction, there is no precipitate formed as the products are souble.
(6) Reaction for C + D
+
BaS +

In this reaction, BaS is formed as precipitate as it do not dissolve.