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Electrons are added into the outermost what in groups 1 & 2

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S orbital.

Group 1 elements have a general configuration
ns^(1), where n represents the highest occupied Principal Energy Level. For example, Lithium has the valence configuration
2s^(1) whereas Cesium has
6s^(1). Both of them belong to Group 1 of Periodic Table.

Group 2 elements have a general configuration of
ns^(2). For example, Magnesium has
3s^(2) as its outer shell configuration while Strontium has the same as
5s^(2).

We see that in both the cases, the outermost S orbital is being filled.

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