Our numeric system is positional, meaning that each digit has a different value, depending on the position it is.
So, starting from the left, we have the digit of units, then the tens, the hundred, the thousand...Each time you go a digit to the left, the value increases by a scale of ten.
In formula, the coefficient of the n-th digit from the right is

In your case, the 3's are in the fourth and fifth position, which means that the 3 in fourth position is worth

whereas the 3 in fifth position is worth
