k = 63 mL/g
The equation for the straight line has the form
V = km +b
The formula for the slope k is
k = ΔV/Δm = (V₂ -V₁)/(m₂ - m₁)
So, we pick any two points on the line, preferably as far apart as possible.
I will choose the points (0.77, 50) and (0.10, 8). Then
k = (50 mL – 8 mL)/(0.77 g – 0.10 g) = 42 mL/0.67 g = 63 mL/g
In other words, you get 63 mLCO₂ for every 1 g CaCO₃.