So basically, you have to make two separate equations for the speed of each girl.
Angelina would be 20m + 20(15), with m being the minutes she has traveled.
Angelina's sister would be 25m, since she doesn't have the starting advantage that Angelina has.
So you would have to make them equal to each other to see what the value of m should be so that the girls have traveled the same distance (when Angelina's sister catches up to Angelina). So I'll then solve the equation.
20m + 20(15) = 25m
20(15) = 5m subtract 20m from each side
300 = 5m simplify the 20(15)
60 = m divide both sides by 5
So Angelina's sister will have caught up to her after 60 minutes.
Hope this helps!