They are using two different ways to name angles here.
Let's start with the first one. MNL is going to be the same as angle N.
It is vertical to the angle already given (37 degrees). Vertical angles are equal.
MNL = 37 degrees.
The next one is just labeled M, but it could also be called LMN.
To find this angle, you will need to subtract 90 (the right angle) and 37 (angle N) from 180 (because all 3 angles in a triangle equal 180 and we know 2 of them)
180 - 90 - 37 = 53 degrees.