However you are answering, the way you wrote it should be fine. I'm just going to check to see that it is correct.
-2[3x - (b + 2x) + (x - 3b)] Remove the inside brackets ()
-2[3x - b - 2x + x - 3b] Collect like terms inside the square brackets.
-2[ 3x - 2x + x - b - 3b]
-2[2x - 4b] Now remove the square brackets.
-4x + 8b So your answer and mine agree.
Just write it as you see it.