Minor point: the quadrilateral is STWR, not STRW. Vertices are named in order.
The measure of angle T is half the measure of arc WRS. The measure of angle R is half the measure of arc STW. The sum of the measures of the two arcs is the measure of a circle, 360°, so you have
... T + R = (WRS)/2 + (STW)/2
... ... = (WRS + STW)/2
... ... = 360°/2 = 180°
Since the sum of T and R is 180°, they are supplementary.