12:00 will have both hands pointing up
12:30 will have the straight line at the half past part but it will not be exactly on the 12
3:45 it will be past the 3 and exactly on 45 so it will not work
And 6:00 will be a straight line as one hand will be at the 12 and and it will be straight on the 6 as it is on the hour so the answer is d