The cotangent function is defined as the ratio between cosine and sine of a given angle, i.e.
![\cot(x) = (\cos(x))/(\sin(x))](https://img.qammunity.org/2019/formulas/mathematics/high-school/jxt3ej3t2o7qdnybsovhvjnofc66hc3v84.png)
Since you can't have zero at the denominator, the cotangent function is not defined when the sine is zero.
Let's look at your option:
, so the cotangent is defined here
, so the cotangent is not defined here
, so the cotangent is defined here
, so the cotangent is defined here