Answer : The initial activity, in microcuries, of the sample was, 120.9 μci
Explanation :
Half-life = 32.5 days
First we have to calculate the rate constant, we use the formula :
![k=(0.693)/(t_(1/2))](https://img.qammunity.org/2019/formulas/biology/high-school/8efd9tonxuepcs3683fwlyi5g02opc4tj1.png)
![k=\frac{0.693}{32.5\text{ days}}](https://img.qammunity.org/2019/formulas/chemistry/college/5qimam36kfb0no3342jh51nx6qxxsx5bf9.png)
![k=0.0213\text{ days}^(-1)](https://img.qammunity.org/2019/formulas/chemistry/college/m89x85pv6irgfs1qbu2l0zbhdkhkkayu81.png)
Now we have to calculate the time passed.
Expression for rate law for first order kinetics is given by:
![t=(2.303)/(k)\log(a)/(a-x)](https://img.qammunity.org/2019/formulas/biology/high-school/1zz9efqb3ztmpmv1vmtzm2lfy6bswrh43h.png)
where,
k = rate constant =
![0.0213\text{ days}^(-1)](https://img.qammunity.org/2019/formulas/chemistry/college/2tkaofbf1lgp1sukw4b7zaedln0xczuijd.png)
t = time passed by the sample = 162.5 days
a = initial amount of the reactant = ?
a - x = amount left after decay process = 3.8 μci
Now put all the given values in above equation, we get
![162.5=(2.303)/(0.0213)\log(a)/(3.8\mu ci)](https://img.qammunity.org/2019/formulas/chemistry/college/ylkzp7t8mzrcil1agmdby2hgt4arg7laqb.png)
![a=120.9\mu ci](https://img.qammunity.org/2019/formulas/chemistry/college/k5bkr0ahpgjoyb7zi2y2zt8uew0ryj3cl7.png)
Therefore, the initial activity, in microcuries, of the sample was, 120.9 μci