Let’s try to look at each one.
First one:
4(x+3)+2x=6(x+2)
We can multiply.
4x+12+2x=6x+12
By looking at this, you can tell it’s equal due to the fact when you add like terms, they will have to same answer.
Second one:
5+2(3+2x)=x+3(x+1)
Let’s multiply.
5+6+4x=x+3x+1
I can already tell this isn’t equal. One has +11 and the other has +1. To make sure, let’s have x=1
5+2(3+2)=1+3(1+1)
5+2(5)=1+3(2)
5+10=1+6
15=7
7 and 15 are not the same number, so the second one doesn’t have any solutions.