Answer : The correct answer for amount of radioisotope remain in 2030 is 0.619 g .
Radioactive Decay is emission of radiations ( in form of alpha , beta particle etc ) by unstable atom .
Radioactive decay is FIRST ORDER reaction . So , the equation of first order can be used to find decay constant , amount of radioisotopes or half life .
The equation for radioactive decay is given as :
![ln ((N)/(N_0)) = -k * t](https://img.qammunity.org/2019/formulas/chemistry/college/1nykykxs2i9m7cp8cqmmo62sbzo2z5o0p2.png)
Where : N = amount of radioisotope at time t
N₀ = amount of radioisotope initially present
k = decay constant t = time
Half life :
It is time when amount of radioisotope decrease to 50 % of its original amount . Half life
and decay constant can be related :
![T_(1)/(2) = (ln 2 )/(k) = (0.693)/(k)](https://img.qammunity.org/2019/formulas/chemistry/college/gsbom3jm25x85znxkjter64yrhpafq4big.png)
Following are the steps can be used to determine amount of radioisotope (N) :
1) To find decay constant :
Given :
= 28 yrs
Decay constant can be calculated using half life by plugging value in half life formula :
![28 yrs = (0.693)/(k)](https://img.qammunity.org/2019/formulas/chemistry/college/aqa0bvy7dni1ha4qbcfhmvcykc0gsnszxw.png)
On multiplying both side by k
![28 yrs * k= (0.693)/(k) *k](https://img.qammunity.org/2019/formulas/chemistry/college/ligpr4u1gq6ww151r5ps4c3m5hjh5zom23.png)
On dividing both side by 28 yrs
![(28 yrs * k)/(28 yrs) = (0.693)/(28 yrs)](https://img.qammunity.org/2019/formulas/chemistry/college/ki5sc55f623ywb18fopxpu094vluertbbx.png)
k = 0.02475 yrs⁻¹
2) To find amount of radioisotope (N):
Given : Amount of radioisotope originally present = 3.5 g
Time = 2030 - 1960 = 70 yrs
decay constant = 0.02475 yrs⁻¹
Amount of radioisotope (N) = ?
Plugging these values in the formula as:
![ln ((N)/(3.5 ) ) = - 0.02475 yrs^-^1 * 70 yrs](https://img.qammunity.org/2019/formulas/chemistry/college/vkozjh4dudlac1t70t2zcm9dlwl4jtn61w.png)
![ln ((N)/(3.5 ) ) = - 1.7325](https://img.qammunity.org/2019/formulas/chemistry/college/l1mzip0jqwezam77oe3hnl9yb9chu2q512.png)
can be converted using the formula (
)
ln N - ln (3.5 ) = - 1.7325
(ln 3.5 = 1.253 )
ln N -1.253 = -1.7325
Adding both side 1.253
ln N -1.253 + 1.253 = -1.7325 + 1.253
ln N = -0.4795
Taking anti ln of -0.4795
N = 0.619 g
Hence amount of radioisotope remained in 2030 is 0.619 g