empirical formula is the simplest ratio of whole numbers of components in a compound
for 100 g of the compound
N O
mass 22.6 g 77.4 g
number of moles 22.6 g / 14 g/mol 77.4 g / 16 g/mol
= 1.61 mol = 4.84 mol
divide by the least number of moles
1.61 / 1.61 = 1.00 4.84 / 1.61 = 3.01
rounded off to nearest whole numbers
N - 1
O - 3
therefore empirical formula - NO₃