Molar mass(C)= 12.0 g/mol
Molar mass (O2)=2*16.0=32.0 g/mol
Molar mass (CO2)=44.0 g/mol
18g C*1mol C/12 g C = 1.5 mol C
C + O2 → CO2
from reaction 1 mol 1 mol 1 mol
from problem 1.5 mol 1.5 mol 1.5 mol
1.5 mol O2*32 g O2/1 mol O2 = 48 g O2
In reality this reaction requires only 48 g O2 for 18 g carbon.
And from 18 g carbon you can get only
1.5 mol CO2*44 g CO2/1 mol CO2=66 g CO2
But these problem has 72g CO2. The best that we can think, it is a mix of CO2 and O2.
So to find all amount of O2 that was added for the reaction (probably people who wrote this problem wanted this)
we need (the mix of 72g - mass of carbon 18 g)= 54 g.
So the only answer that is possible is 2.) 54 g.