Answer: The mass difference between the two is 7.38 grams.
Step-by-step explanation:
To calculate the number of moles, we use the equation given by ideal gas follows:
![PV=nRT](https://img.qammunity.org/2020/formulas/chemistry/high-school/uelah1l4d86yyc7nr57q25hwn1eullbhy3.png)
where,
P = pressure = 125 psi = 8.50 atm (Conversion factor: 1 atm = 14.7 psi)
V = Volume = 855 mL = 0.855 L (Conversion factor: 1 L = 1000 mL)
T = Temperature =
![25^oC=[25+273]K=298K](https://img.qammunity.org/2020/formulas/physics/high-school/h3swi627jfkpg7vx7in8p5pe35bz1gwehq.png)
R = Gas constant =
![0.0821\text{ L. atm }mol^(-1)K^(-1)](https://img.qammunity.org/2020/formulas/chemistry/college/or3fnut01uac9jlkn35p8svtyqd1qim7k7.png)
n = number of moles = ?
Putting values in above equation, we get:
![8.50atm* 0.855L=n* 0.0821\text{ L atm }mol^(-1)K^(-1)* 298K\\\\n=(8.50* 0.855)/(0.0821* 298)=0.297mol](https://img.qammunity.org/2020/formulas/chemistry/college/51wyzb5gmpbkkh7qwuootyktgbj650yq16.png)
To calculate the number of moles, we use the equation:
.....(1)
Moles of air = 0.297 moles
Average molar mass of air = 28.8 g/mol
Putting values in equation 1, we get:
![0.297mol=\frac{\text{Mass of air}}{28.8g/mol}\\\\\text{Mass of air}=(0.297mol* 28.8g/mol)=8.56g](https://img.qammunity.org/2020/formulas/chemistry/college/46rzrpiyl4uzy07szfr7z5dbzl74h6tsu1.png)
Mass of air,
= 8.56 g
Moles of helium = 0.297 moles
Molar mass of helium = 4 g/mol
Putting values in equation 1, we get:
![0.297mol=\frac{\text{Mass of helium}}{4g/mol}\\\\\text{Mass of helium}=(0.297mol* 4g/mol)=1.18g](https://img.qammunity.org/2020/formulas/chemistry/college/7t4rz1artty6n3yf4acdcmqfwrz9us058j.png)
Mass of helium,
= 1.18 g
Calculating the mass difference between the two:
![\Delta m=m_1-m_2](https://img.qammunity.org/2020/formulas/chemistry/college/ht6ary5adze5g9qmqxjlcfwz3dvw4oz4ok.png)
![\Delta m=(8.56-1.18)g=7.38g](https://img.qammunity.org/2020/formulas/chemistry/college/wnszlgvrdlv1yy4vc125miz8zmobit19d5.png)
Hence, the mass difference between the two is 7.38 grams.