Answer:
Sam will need 3 tablespoons of chili powder to make 1/2 the recipe.
Explanation:
We have to first find out out how many tablespoons of chili powder are needed for every liter of chili.
We know that 2/3 tablespoons make 1/9 liters of chili, therefore:

So this is 6 tablespoons of chili powder per liter of chili.
Now if Sam's recipe is for 1 liter of chili, and he wants to make 1/2 the recipe, this means that Sam is making 1/2 liters of chili.
For 1/2 liters of chili we need

So our answer is 3 tablespoons of chill powder.