65.2k views
3 votes
The oxide of titanium,TiO2 is used as a "whitener" in toothpaste.It is obtained from the ore iron (II) titanate,FeTiO3.What is the change,if any,in the oxidation number (oxidation state) of titanium in the reaction

1 Answer

3 votes

Answer:

There is no change in the oxidation number (oxidation state) of titanium in the reaction

Step-by-step explanation:

TiO2

⇒ The oxidation number of O = -2

⇒ Since we have O2, this makes 2*-2 = -4

⇒ The oxation number of Ti and O2 together should be 0

⇒The oxidation number of Ti is +4

For FeTiO3, it's more complicate because Fe can have several oxidation numbers.

Since FeTiO3 has three short metal–oxygen bonds in the octahedron and three long metal -oxygen bonds.

The valences, obtained from the bond lengths by the bond valence method, is +2 anapproximately which can be rounded off to oxidation stated +4, respectively for Fe and Ti.

FeTiO3

⇒ The oxidation number of O = -2

⇒ We have O3 so this makes 3*-2 = -6

⇒Fe has an oxidation state of +2

⇒The oxidation state of Fe, Ti and O3 together should be 0

⇒Ti has an oxidation state of +4

This means Titanium doesn't change it's oxidation number.

There is no change in the oxidation number (oxidation state) of titanium in the reaction

User Neotrixs
by
5.9k points