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A. Match each type of titration to its pH at the equivalence point.

Weak acid, strong base
Strong acid, strong base
Weak base, strong acid

pH less than 7
pH equal to 7
pH greater than 7

b. A 56.0 mL volume of 0.25 M HBr is titrated with 0.50 M KOH. Calculate the pH after addition of 28.0 mL of KOH.
c. Consider the titration of 50.0 mL of 0.20 M NH3 (Kb=1.8 x 10^-5) with 0.20 M HNO3. Calculate the pH after addition of 50.0 mL of the titrant.
d. A 30.0 mL volume of 0.50 M CH3COOH (Ka = 1.8 x 10^-5) was titrated with 0.50 M NaOH. Calculate the pH after addition of 30.0 mL of NaOH.

User FredRoger
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1 Answer

3 votes

Answer:answers are in the explanation

Step-by-step explanation:

(a). pH less than 7 between 1 - 3.5 are strong acid, and between 4.5-6.9 weak acid.

pH greater than 7; between 10-14 is a strong base, and between 7.1 - 9, it is weakly basic.

(b). Equation of reaction;

HBr + KOH ---------> KBr + H2O

One mole of HBr reacts with one mole of KOH to give one Mole of KBr and one mole of H2O

Calculating the mmol, we have;

mmol KOH = 28.0 ml × 0.50 M

mmol KOH= 14 mmol

mmol of HBr= 56 ml × 0.25M

mmol of HBr= 14 mmol

Both HBr and KOH are used up in the reaction, which leaves only the product,KBr and H2O.

The pH here is greater than 7

(C). [NH4^+] = 0.20 mol L^-1 × 50 ml. L^-1 ÷ 50 mL + 50mL

= 0.10 M

Ka=Kw/kb

10^-14/ 1.8× 10^-5

Ka= 5.56 ×10^-10

Therefore, ka= x^2 / 0.20

5.56e-10 = x^2/0.20

x= (0.20 × 5.56e-10)^2

x= 1.05 × 10^-5

pH = -log [H+]

pH= - log[1.05 × 10^-5]

pH = 4.98

Acidic(less than 7)

(c). 0.5 × 20/40

= 0.25 M

Ka= Kw/kb

kb= 10^-14/1.8× 10^-5

Kb = 5.56×10^-10

x= (5.56×10^-10 × 0.5)^2

x= 1.667×10^-5 M

pH will be basic

User Alakmar Shafin
by
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