Final answer:
The presence of a polar or charged head group attached to the phosphate allows phospholipids to interact with the aqueous environment in both extracellular and intracellular cytosolic environments.
Step-by-step explanation:
The feature of phospholipids that allows them to interact with the aqueous environment in both the extracellular and intracellular cytosolic environments is the presence of a polar or charged head group attached to the phosphate. Phospholipids have a hydrophobic tail region and a hydrophilic head region. The polar head group interacts with the surrounding water molecules, while the hydrophobic tails cluster together, forming a barrier against the water.