Final answer:
To produce exactly 14.5 moles of CO2 from the reaction of methane with oxygen, 14.5 moles of CH4 are required according to the balanced chemical equation.
Step-by-step explanation:
When solving a stoichiometry problem, such as determining how many moles of CH4 are needed to produce a certain amount of CO2, it's important to start with the balanced chemical equation: CH4 + 2 O2 → CO2 + 2 H2O. According to the stoichiometry of the reaction, 1 mole of methane reacts with 2 moles of oxygen to produce 1 mole of carbon dioxide. Thus, to produce 14.5 moles of CO2, you would need 14.5 moles of CH4, since they react on a 1:1 molar basis.