Answer:Ba

Step-by-step explanation:
option A:
is an anion and
is also an anion.So,there is no reaction.
option B:
reacts with
to form
.
Since
is a first group element,all its salts are soluble in water.
Hence no precipitate is formed.
option C:
reacts with
to form
.
Since
is a first group element,all its salts are soluble in water.
Hence no precipitate is formed.
option D:
reacts with
to form
.
Solubility of sulphates of second group elements decrease down the group.
So,
is a precipitate.