Final answer:
The heat capacity of the bomb calorimeter is found to be -21.61 kJ/°C, which indicates that it absorbs 21.61 kJ of heat for each degree Celsius temperature increase resulting from the combustion of a substance within it.
Step-by-step explanation:
To determine the heat capacity of the bomb calorimeter, we will use the provided information about the combustion of methane: the burning of 6.79 g of methane, a temperature change of 15.7°C, and an energy of combustion being -802 kJ/mol CH4. First, we calculate the moles of methane combusted using its molar mass (approximately 16.04 g/mol).
Moles of methane = 6.79 g / 16.04 g/mol = 0.423 mol
Next, we calculate the total heat released during the combustion:
Total heat (q) = -802 kJ/mol × 0.423 mol = -339.2 kJ
Now, we use the formula q = C×ΔT to find the heat capacity of the bomb where q is the heat released, C is the heat capacity, and ΔT is the temperature change. Solving for C:
C = q /ΔT = -339.2 kJ / 15.7°C = -21.61 kJ/°C
The heat capacity of the bomb calorimeter is -21.61 kJ/°C, which means that for every degree Celsius the temperature rises, the calorimeter absorbs 21.61 kJ of heat.