Answer:
Fourth option: Vertical Angles Theorem.
Explanation:
The missing picture is attached.
It is important to remember that when parallel lines are cut by another line (This line is called "Transversal"), several angles are formed. These angles can be made into pair of angles that have the same measure.
Vertical angles are the opposite pair of angles that share the same vertex and they are congruent whether the lines are parallel or not.
Knowing this, we can identify in the picture that:
and
are opposite and share the same vertex; therefore they are Vertical angles.
and
are opposite and share the same vertex; therefore they are Vertical angles.
Then:
and
by the Vertical Angles Theorem.