Answer:
![55.2kgNa_(3)AlF_(6)](https://img.qammunity.org/2020/formulas/chemistry/college/vrxfac03g38dgrm1ccxh50gkj0bg4x1dz4.png)
Step-by-step explanation:
1. First balance the equation for the synthesis of cryolite:
![Al_(2)O_(3)_((s))+6NaOH_((l))+12HF_((g))=2Na_(3)AlF_(6)+9H_(2)O_((g))](https://img.qammunity.org/2020/formulas/chemistry/college/urmn7xl1a8hwfr87qb2yx849fv3vzpkide.png)
2. Find the limiting reagent between the
and
![HF](https://img.qammunity.org/2020/formulas/physics/high-school/ichxrikmzlorlazz8orewjtxl0j5w5wnjq.png)
- First calculate the number of moles of each compound using its molar mass and the mass that reacted completely:
![13.4kgAl_(2)O_(3)*(1molAl_(2)O_(3))/(101.96gAl_(2)O_(3))*(1000g)/(1kg)=131molesAl_(2)O_(3)](https://img.qammunity.org/2020/formulas/chemistry/college/ej8rx3ka0p1r9u1cfotmkvjfusfe2ogtlr.png)
![55.4kgNaOH*(1molNaOH)/(40kgNaOH)*(1000g)/(1kg)=1385molesNaOH](https://img.qammunity.org/2020/formulas/chemistry/college/882fe5nrdk1zlxmve2f1069e3mh3duhahk.png)
![55.4kgHF*(1molHF)/(20kgHF)*(1000g)/(1kg)=2770molesHF](https://img.qammunity.org/2020/formulas/chemistry/college/axtnypqyermtjhhjojum0ubicfjms1zhj8.png)
- Divide the number of moles obtained between the stoichiometric coefficient of each compound in the chemical reaction:
![Al_(2)O_(3):(131)/(1)=131](https://img.qammunity.org/2020/formulas/chemistry/college/19s199vvm13gs3r6jekgugi9857gmndgt4.png)
![NaOH:(1385)/(6)=231](https://img.qammunity.org/2020/formulas/chemistry/college/8dee528x4jtnt16w7uji11sn823y2eictt.png)
![HF:(2770)/(12)=231](https://img.qammunity.org/2020/formulas/chemistry/college/31243bf7zhqu3gmxoa1ar1fvvfh832hkhc.png)
The
is the limiting reagent because it has the smallest number.
3. Find the mass of cryolite produced:
![13.4kgAl_(2)O_(3)*(1molAl_(2)O_(3))/(0.10196kgAl_(2)O_(3))*(2molesNa_(3)AlF_(6))/(1molAl_(2)O_(3))*(0.20994kgNa_(3)AlF_(6))/(1molNa_(3)AlF_(6))=55.2kgNa_(3)AlF_(6)](https://img.qammunity.org/2020/formulas/chemistry/college/pr458f3rbh6wy2lf6yhoto7wa9bgo0g50b.png)