#1. Answer:
0.449 mole
Solution and explanation:
We are given;
Volume of oxygen gas,V = 75.0 mL or 0.075 L
Pressure, P = 145 atm
Temperature, T = 22° C or 22 + 273 = 295 K
We are required to calculate the moles of Oxygen gas
We are going to use the ideal gas equation which states;
PV =nRT where, P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant,(0.082057 L atm/mol.K) and T is the temperature.
Therefore, to get n we use;



Therefore; the number of moles of Oxygen gas is 0.449 mole
# 2. Answer
35,410.99 torr
Solution and Explanation:
We are given
Initial Pressure of the gas, P1 = 30,400 torr
Initial temperature, T1 = 0°C or 273 K
Final temperature, T2 = 45°C or 318 K
We are required to find the final pressure, P1,
- According to the pressure Law, pressure of a gas and its absolute temperature vary direct proportionally to each other at constant volume.
Therefore,

At varying temperature and pressure;

Thus;



Therefore; the new pressure in the container is 35,410.99 torr