No, in a head on collision between two vehicles, there is no force acting on the persons in the car that propels them toward the windshield.
Explanation:
When there is head on collision between two vehicles, then according to Newton’s third law, each vehicle will be exerting equal amount of force in opposite direction to each other. This action and reaction during collision leads to stop the vehicles at the end of collision.
But this is occurring outside the car during collision. In the interior of the car, a balanced force acts between the driver and any person inside the car or with the car itself, before collision. This balanced force can be termed as inertial force in this case.
As per Newton’s first law, this inertial force is the force exerted by the persons seated in the car and which prevents the person’s change in its state of motion or rest.
So, while car is moving the inertial force will act making the body move in the same frame of reference as car. After head on collision, the net force on the vehicles will become zero and they will stop.