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1.) What is the bond order of each of the following bonds?

C=N C≡N C—N
Put them in order of increasing bond dissociation energy (BDE).
Is there a connection between bond order and BDE?

2.)Using only the periodic table, select the most electronegative atom in each of the following sets:

As, Se, Br, I
Al, B, C, Si
Ge, As, P, Sn
Li, Rb, Be, Sr

3.)Arrange the bonds in each of the following sets in order of increasing polarity:

C-F, O-F, Be-F
Be-Cl, Br-Cl, C-Cl
C-Cl, C-O, C-H

4.) Draw a Lewis structure for

SiH4
BrF3
H2CO

2 Answers

2 votes

Final answer:

In question 1, the bond order and bond dissociation energy (BDE) are related. As the bond order increases, the BDE increases. This is because a higher bond order indicates a stronger bond, which requires more energy to break.

Step-by-step explanation:

Question 1:

  1. The bond order of the following bonds is:
    - C=N: bond order 2
    - C≡N: bond order 3
    - C—N: bond order 1
    The bond dissociation energy (BDE) increases as the bond order increases.
  2. The most electronegative atom in each set is:
    - As, Se, Br, I: I is the most electronegative.
    - Al, B, C, Si: C is the most electronegative.
    - Ge, As, P, Sn: As is the most electronegative.
    - Li, Rb, Be, Sr: Li is the most electronegative.
  3. The bonds in each set arranged in order of increasing polarity are:
    - C-F, O-F, Be-F: Be-F < C-F < O-F
    - Be-Cl, Br-Cl, C-Cl: C-Cl < Be-Cl < Br-Cl
    - C-Cl, C-O, C-H: C-H < C-O < C-Cl
  4. The Lewis structures for the given molecules are:
    - SiH4: H-Si-H-H
    - BrF3: Br-F-F-F
    - H2CO: H-C=O

Question 2:

  1. In question 1, the bond order and bond dissociation energy (BDE) are related. As the bond order increases, the BDE increases. This is because a higher bond order indicates a stronger bond, which requires more energy to break.
User Blasio
by
5.1k points
2 votes

Answer:

1. C—N Bond of 1, C≡N Bond order 3, C=N Bond Order 2

(least BDE) C—N < C=N < C≡N (Most BDE)

2. Br

C

P

Be

3. (least polar) O-F, C-F, Be-F (Most polar)

(Least) Br-Cl, C-Cl, Be-Cl (Most)

(least)C-H, C-Cl, C-O (most)

Step-by-step explanation:

For lewis, please google them

User Akshay Sunderwani
by
5.7k points