Answer:
2:1
Step-by-step explanation:
The Law of Multiple Proportions states that when two elements A and B combine to form two or more compounds, the masses of B that combine with a given mass of A are in the ratios of small whole numbers.
That is, if one compound has a ratio r₁ and the other has a ratio r₂, the ratio of the ratios r is in small whole numbers.
1. Compound 1
Mass of O = 100.0 - 61.4 = 38.6 g
![r_(1) = \frac{\text{mass of O}}{\text{mass of V}} = ( 38.6)/(61.4) = 0.6287](https://img.qammunity.org/2020/formulas/chemistry/high-school/j4nnb1x6wjy6t6gpoaj19zrd046hmis9ir.png)
2. Compound 2
Mass of O = 100.0 - 76.1 = 23.9 g
![r_(2) = ( 23.9)/(76.1) = 0.3141](https://img.qammunity.org/2020/formulas/chemistry/high-school/fla6o1pvn321mh7ez4vjqnz9q7spfe46b7.png)
3. Ratio of the ratios
![r = (r_(1))/(r_(2)) = ( 0.6287)/(0.3141) = (2.00)/(1) \approx 2\\\\\text{The relative amounts of O per gram of V are in the ratio }\boxed{\mathbf{(2)/(1)}}](https://img.qammunity.org/2020/formulas/chemistry/high-school/7r5qoh1afm5l22lzmox6c1wfujuud1teql.png)
For example. the compounds might be VO₂ and VO.