200k views
3 votes
The halpy of vaporization of H2O at 1 atm and 100 C is 2259 kJ/kg. The heat capacity of liquid water is 4.19 kJ/kg.C, and the heat capacity of water vapor is 1.9 kJ/kg-C. H20 at 10 bar boils at 179.9 C. What is the enthalpy of vaporization of H20 at 10 bar? You can neglect the effect of pressure. e 2076 kJ/kg e 1924 kJ/kg e 2259 kJ/kg 2442 kJ/kg 2594 kJ/kg None of the above

1 Answer

2 votes

Answer: Option (a) is the correct answer.

Step-by-step explanation:

The given data is as follows.


C_(p)_(liquid) = 4.19
kJ/kg ^(o)C


C_(p)_(vaporization) = 1.9
kJ/kg ^(o)C

Heat of vaporization (
\DeltaH^(o)_(vap)) at 1 atm and
100^(o)C is 2259 kJ/kg


H^(o)_(liquid) = 0

Therefore, calculate the enthalpy of water vapor at 1 atm and
100^(o)C as follows.


H^(o)_(vap) =
H^(o)_(liquid) +
\DeltaH^(o)_(vap)

= 0 + 2259 kJ/kg

= 2259 kJ/kg

As the desired temperature is given
179.9^(o)C and effect of pressure is not considered. Hence, enthalpy of liquid water at 10 bar and
179.9^(o)C is calculated as follows.


H^(D)_(liq) = H^(o)_(liquid) + C_(p)_(liquid)(T_(D) - T_(o))

=
0 + 4.19 kJ/kg ^(o)C * (179.9^(o)C - 100^(o)C)

= 334.781 kJ/kg

Hence, enthalpy of water vapor at 10 bar and
179.9^(o)C is calculated as follows.


H^(D)_(vap) = H^(o)_(vap) + C_(p)_(vap) * (T_(D) - T_(o))


H^(D)_(vap) =
2259 kJ/kg + 1.9 * (179.9 - 100)

= 2410.81 kJ/kg

Therefore, calculate the latent heat of vaporization at 10 bar and
179.9^(o)C as follows.


\Delta H^(D)_(vap) =
H^(D)_(vap) - H^(D)_(liq)

= 2410.81 kJ/kg - 334.781 kJ/kg

= 2076.029 kJ/kg

or, = 2076 kJ/kg

Thus, we can conclude that at 10 bar and
179.9^(o)C latent heat of vaporization is 2076 kJ/kg.

User Mlathe
by
7.9k points